Organometallic Chemistry Laboratory
Our research interests cover broad areas of organometallic chemistry, which include the synthesis of new complexes having novel structures, development of more efficient, more selective catalysts for olefin polymerization and organic synthesis, and exploration of new chemical transformation processes by use of organometallic compounds. Much of our work lies at the interfaces between inorganic, organic, polymer and material chemistries. Researchers in this laboratory have access to the state-of-the-art inert atmosphere workstations and other modern facilities for organometallic and related researches.
- New single-site catalysts for regio- and stereospecific olefin polymerization and copolymerization
- New organometallic catalysts for efficient organic synthesis
- Synthesis and synergistic reactivity of rare earth metal hydride clusters
- Development of novel organic electroluminescence (EL) materials
- September 19, 2011
- New metal hydride clusters provide insights into hydrogen storage
- December 03,2010
- From pollution to solution
'Green' catalysts transform carbon dioxide gas into valuable building blocks for organic synthesis![]()
- February 05, 2010
- Precision molecular assembly
A finely tuned rare-earth metal catalyzes the exact interactions needed for site-selective molecular synthesis![]()
- Pan, L., Zhang, K., Nishiura, M., Hou, Z.:
"Chain-Shuttling Polymerization at Two Different Scandium Sites: Regio- and Stereospecific "One-Pot" Block Copolymerization of Styrene, Isoprene, and Butadiene"
Angew. Chem. Int. Ed., 50, 12012-12015 (2011). - Guan, B., Hou, Z.:
"Rare-Earth-Catalyzed C-H Bond Addition of Pyridine to Olefins"
J. Am. Chem. Soc., 133, 18086-18089 (2011). - Oyamada, J. , Nishiura, M., Hou, Z.:
"Scandium-Catalyzed Silylation of Aromatic C-H Bonds"
Angew. Chem. Int. Ed., 50, 10720-10723 (2011). - Shima, T., Luo, Y. , Stewart, T. , Bau, R., Mclntyre, G. J., Mason, S. A., Hou, Z.:
"Molecular Heterometallic Hydride Clusters Composed of Rare-Earth and d-Trantion Metals"
Nature Chem., 3, 814-820 (2011). - Ohishi, T., Zhang, L., Nishiura, M., Hou, Z.:
"Carboxylation of Alkylboranes by N-Heterocyclic Carbene Copper Catalysts: Synthesis of Carboxylic Acids from Terminal Alkenes and Carbon Dioxide"
Angew. Chem. Int. Ed., 50, 8114-8117 (2011). - Chen, J., Shima, T., Hou,. Z.:
"Rare-Earth Polyhydride Complexes Bearing Bis(phosphinophenyl)amido Pincer Ligands."
Angew. Chem. Int. Ed. 50, 1857-1860 (2011). - Li, S., Cheng, J., Chen, Y., Nishiura, M., Hou, Z.:
"Rare-Earth Metal Boryl Complexes: Synthesis, Structure, and Insertion of a Carbodiimide and Carbon Monoxide"
Angew. Chem. Int. Ed., 50, 6360-6363 (2011). - Zhang, L. ., Cheng, J., Ohishi , T., and Z. Hou.:
"Copper-Catalyzed Direct Carboxylation of C-H Bonds with Carbon Dioxide"
Angew. Chem. Int. Ed., 49, 8670-8673 (2010). - Nishiura, M., Hou, Z.:
"Novel polymerization catalysts and hydride clusters from rare-earth metal dialkyls "
Nature Chem., 2, 257-268 (2010). - Takimoto, M., Usami, S., Hou, Z.:
"Scandium-Catalyzed Regio- and Stereospecific Methylalumination of Silyloxy/Alkoxy-Substituted Alkynes and Alkenes."
J. Am. Chem. Soc., 131, 18266-18268 (2009).
Principal Investigator
- Zhaomin HOU
- Chief Scientist
Staff Scientist
- Masayoshi NISHIURA
- Senior Research Scientist
- Takanori SHIMA
- Senior Research Scientist
- Masanori TAKIMOTO
- Senior Research Scientist
Postdoctoral Fellow
- Liang ZHANG
- Foreign Postdoctoral Researcher
- Jianhua CHENG
- Contract Researcher
- Juzo OYAMADA
- Postdoctoral Researcher
- Bingtao GUAN
- Postdoctoral Researcher
- Virendra Kumar RAI
- Postdoctoral Researcher
- Daisuke KAWAI
- Postdoctoral Researcher
- Hongxia ZHANG
- Postdoctoral Researcher
- Koji NEMOTO
- Postdoctoral Researcher
- Baoli WANG
- Postdoctoral Researcher
- Yoshinori ENDO
- Postdoctoral Researcher
- Wylie O Wing NIEN
- Postdoctoral Researcher
- Guoyong SONG
- Visiting Researcher
Student Trainee
- Atsushi UENO
- Junior Research Associate
- Shaowei HU
- International Program Associate
- Ting-Ting LI
- International Program Associate
- Bhushan Vinayak PATIL
- International Program Associate
- Carry Beatrice MARIE-PIERRE
- Intern
Administrative Assistant
- Hiromi SUGIYAMA
- Assistant
Others
- Hisashi SOGA
- Agency Staff
- Akiko KARUBE
- Part-timer2

