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Condensed Molecular Materials Laboratory
Reizo KATO
Chief Scientist
Reizo KATO (D.Sci.)
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Research Areas

Synthesis, characterization and design of molecular materials, especially molecular metals ( superconductors ), have been undertaken. Molecular conductors exhibit a variety of physical properties which can be systematically understood on the basis of "simple" and "clear" electronic structures. From a chemical point of view, the most fascinating character of the molecular conductor is its "designability", that is, we can finely control solid state properties with chemical modifications of the molecule. The newly synthesized materials are characterized by the X-ray diffraction method and physical measurements (electrical conductivity, etc.). The electronic structure is investigated by the simple band structure calculation. All these results are devoted to the design of new molecular materials.

Research Subject

  1. Construction and Electronic Properties of New Supramolecular Assemblies
  2. Physical and Chemical Control of the Electronic State of the Molecular Conductor
  3. Interrelation between the Crystal Structure and the Electrical Property

Related links

  1. RIKEN Advanced Science Institute Website_Laboratories PageNew Window
  2. Individual Website Laboratory PageNew Window

Press release

August 13, 2009
Mysterious electronic behavior detected in organic Mott insulator
April 30, 2009
First ever development of a two-dimensional zero-gap electric conductor from multi-layered single crystals of organic conductor alpha-(BEDT-TTF)2I3
June 23, 2008
Development of organic Mott FET with field effect transition comparable to that of polycrystal silicon, to produce a new functional field effect transistor from novel materials
January 02,2008
Naked nanowires cover up
Scientists have devised insulated nanowires that could drive the development of nanotechnology devices. New Window
December 19, 2007
Novel means devised to study riddle of superconductivity
Investigation of 'pseudogap phase' points way to high-temperature superconductors. New Window

RIKEN RESEARCH

August 13,2010
A lack of order
A comparative study of two closely related organic insulators highlights the unusual properties of quantum spin liquids New Window
June19, 2009
Electrons narrow the gap
An organic compound provides the rare opportunity to study electrons that behave as if they have no mass New Window
November 14, 2008
Manipulating Electrons with Molecules New Window
October 24, 2008
Forced to insulate
Substrate-induced strain can be used to switch an organic superconductor into an insulator that responds to the application of a voltage New Window
September 19,2008
New clues on organic superconductors
The transport properties of organic conductors are strictly connected to the internal geometry of crystals New Window

List of Selected Publications

  1. Yamamoto, T., Nakazawa, Y., Tamura, M., Nakao, A., Ikemoto, Y., Moriwaki, T., Fukaya, A., Kato, R., and Yakushi, K.:
    "Intradimer Charge Disproportionation in Triclinic-EtMe3P[Pd(dmit)2]2 (dmit: 1,3-Dithiole-2-thione-4,5-dithiolate)"
    J. Phys. Soc. Jpn., 80, 123709/1-4 (2011).
  2. Kawasugi, Y., Yamamoto, H. M., Tajima, N., Fukunaga, T., Tsukagoshi, K., and Kato, R.:
    "Electric-Field-Induced Mott Transition in an Organic Molecular Crystal"
    Phys. Rev. B, 84, 125129/1-9 (2011).
  3. Yamamoto, T., Nakazawa, Y., Tamura, M., Fukunaga, T., Kato, R., and Yakushi, K.:
    "Vibrational Spectra of [Pd(dmit)2] Dimer (dmit = 1,3-dithiole-2-thione-4,5-dithiolate): Methodology for Examining Charge, Inter-Molecular Interactions, and Orbital"
    J. Phys. Soc. Jpn., 80, 074717/1-16 (2011).
  4. Hazama, K., Uji, S., Takahide, Y., Kimata, M., Satsukawa, H., Harada, A., Terashima, T., Kosaka, Y., Yamamoto, H. M., and Kato, R.:
    "Fermi Surface and Interlayer Transport in the Two-Dimensional Magnetic Organic Conductor (Me-3,5-DIP)[Ni(dmit)2]2"
    Phys. Rev. B, 83, 165129/1-9 (2011).
  5. Yamashita, S., Yamamoto, T., Nakazawa, Y., Tamura, M., and Kato, R.:
    "Gapless Spin Liquid of an Organic Triangular Compound Evidenced by Thermodynamic Measurements"
    Nature Communications, 2, 275/1-6 (2011).
  6. Yamashita, M., Nakata, N., Senshu, Y., Nagata, M., Yamamoto, H. M., Kato, R., Shibauchi, T., and Matsuda, Y.:
    "Highly Mobile Gapless Excitations in a Two-Dimensional Candidate Quantum Spin Liquid"
    Science, 328(5983), 1246-1248 (2010).
  7. Kawasugi, Y., Yamamoto, H. M., Tajima, N., Fukunaga, T., Tsukagoshi, K., and Kato, R.:
    "Field-Induced Carrier Delocalization in the Strain-Induced Mott Insulating state of an Organic Superconductor"
    Phys. Rev. Lett., 103(11), 116801/1-4 (2009).
  8. Tajima, N., Sugawara, S., Kato, R., Nishio, Y., and Kajita, K.:
    "Effect of the Zero-Mode Landau Level on Interlayer Magnetoresistance in Multilayer Massless Dirac Fermion Systems"
    Phys. Rev. Lett., 102(17), 176403/1-4 (2009).
  9. Kawasugi, Y., Yamamoto, H. M., Hosoda, M., Tajima, N., Fukunaga, T., Tsukagoshi, K., and Kato, R.:
    "Strain-Induced Superconductor/Insulator Transition and Field Effect in a Thin Single Crystal of Molecular Conductor"
    Appl. Phys. Lett., 92, 243508/1-3 (2008).
  10. Yamamoto, H. M., Kosaka, Y., Maeda, R., Yamaura, J., Nakao, A., Nakamura, T., and Kato, R.:
    "Supramolecular Insulating Networks Sheathing Conducting Nanowires Based on Organic Radical Cations"
    ACS Nano, 2(1), 143-155 (2008).

Members

Principal Investigator

Reizo KATO
Chief Scientist

Staff Scientist

Yugo OSHIMA
Senior Research Scientist
Minoru YAMASHITA
Research Scientist
Hengbo CUI
ASI Research Scientist

Postdoctoral Fellow

Mitsushiro NOMURA
Special Postdoctoral Researcher
Tetsuro KUSAMOTO
Special Postdoctoral Researcher
Masayuki SUDA
Special Postdoctoral Researcher
Hiroki OTAKI
Special Postdoctoral Researcher
Majed ABDEL JAWAD
Foreign Postdoctoral Researcher
Naoko TAKUBO
Contract Researcher
Youichi NAOE
Postdoctoral Researcher
Kohei UEDA
Postdoctoral Researcher
Takao TSUMURAYA
Postdoctoral Researcher

Visiting Research Staff

Hiroshi YAMAMOTO
Senior Visiting Scientist