Nanocomposite Soft Materials Engineering Team
Our team aims to create water-based materials, referred to as "aqua materials", as replacements for conventional plastics. Taking advantage of their unique properties as "moldable, portable water", together with the elaboration of their inner or surface part, we will demonstrate their various applications as intelligent soft materials. We are employing a wide range of chemicals as the components of aqua materials, in order to improve their properties and to realize ultimately environment conscious materials. The challenge of our team also includes the rational design of novel bioinspired materials, by assembling molecules with dynamic and static functions within aqua materials as scaffolds.
- Chiral solid-state hosts based on the molecular imprinting in liquid crystals
- Chiral molecular flasks based on the template reactions in liquid crystal
- Aqua materials; ultimate environment-conscious alternatives to conventional plastic based on hydro-gels
- Mynar,W. Q., Justin, L., Yoshida, M., Lee, E., Lee, M., Okuro, K., Kinbara, K.,and Aida,T.: "Mouldable Water by a Supramolecular Approach Using Clay and a Dendritic Molecular Binder " Nature, 463, 339-343 (2010).
- Ishida, Y., Iwasa, E., Matsuoka, Y., Miyauchi, H.,and Saigo, K.: "An Enantiopure Cyclophane-Type Imidazole with No Central but Planar Chirality." Chemical Communications 3401-3403 (2009).
- Ishida, Y., Kai, Y., Kato, S., Misawa, A., Amano, S., Matsuoka, Y.,and Saigo, K.: "Two-domponent Liquid Crystals as Chiral Reaction Media:Highly Enantioselective Photo-dimerization of an Anthracene Derivative Driven by the Ordered Microenvironment." Angewandte Chemie International Edition 47, 8241-8245 (2008).
- Matsuoka, Y., Ishida, Y., Sasaki, D., Saigo, K.: "Cyclophane-type Imidazolium Salts with Planar Chirality as a New Class of N-Heterocyclic Carbene Precursors." Chemistry - A European Journal 14, 9215-9222 (2008).
- Amano, S., Ishida, Y.,and Saigo, K.: "Solid-state Hosts by the Template Polymerization of Columnar Liquid Crystals: Locked Supramolecular Architectures around Chiral 2-Amino Alcohols." Chemistry - A European Journal 13, 5186-5196 (2007).
- Ishida, Y., Amano, S.,Iwahashi, N.,and Saigo, K.: "Switching of Structural Order in a Cross-linked Polymer Triggered by the Desorption/Adsorption of Guest Molecules." Journal of the American Chemical Society, 128, 13068-13069 (2006).
- Ishii, D., Kinbara, K.,shida, Y.,Ishii, N., Okochi, M., Yohda, M., Aida, T.: "Chaperonin-mediated Stabilization and ATP-triggered Release of Semiconductor Nanoparticles." Nature, 423, 628-632 (2003).
- Ishida, Y.,Amano, S.,Saigo, K.: "Template Polymerization of Columnar Architectures based on the Salts of a Carboxylic Acid and 2-Amino Alcohols: Application to the Molecular Recognition of 2-Amino Alcohols." Chemical Communications 2338-2339 (2003).
- Ishida, Y., Aida, T.: "Homochiral Supramolecular Polymerization of an "S"-shaped Monomer: Translation of Optical Purity into Molecular Weight Distribution." Journal of the American Chemical Society, 124, 14017-14019 (2002).

