Laboratories
Advanced Catalyst Research Team
Zhaomin HOU
Team Leader
Zhaomin HOU (D.Eng.)
mail

Research Areas

This team aims to develop new generations of catalysts which are complementary or superior to the existing ones for more efficient, selective chemical transformations. Particular attention is paid to the precise copolymerization of two or more different olefin/polar monomers to create novel high-performance polymer materials, the development of novel catalytic enantioselective reactions, and the activation and utilization of small molecules inactive under normal conditions.

Research Subject

  1. Search for Advanced Polymerization Catalysts
  2. Search for Advanced Organic Synthesis Catalysts
  3. Development of novel organic electroluminescence (EL) materials

Related links

  1. RIKEN Advanced Science Institute Website_Laboratories PageNew Window

List of Selected Publications

  1. Pan, L., Zhang, K., Nishiura, M., Hou, Z.:
    "Chain-Shuttling Polymerization at Two Different Scandium Sites: Regio- and Stereospecific "One-Pot" Block Copolymerization of Styrene, Isoprene, and Butadiene"
    Angew. Chem. Int. Ed., 2011, 50, 12012-12015 (2011).
  2. Ohishi, T., Zhang, L., Nishiura, M., Hou, Z.:
    "Carboxylation of Alkylboranes by N-Heterocyclic Carbene Copper Catalysts:Synthesis of Carboxylic Acids from Terminal Alkenes and Carbon Dioxide"
    Angew. Chem. Int. Ed., 50, 8114-8117 (2011).
  3. Guan, B., Hou, Z.:
    "Rare-Earth-Catalyzed C-H Bond Addition of pyridine to Olefins"
    J. Am. Chem. Soc., 133, 18086-18089 (2011).
  4. Oyamada, J. , Nishiura, M., Hou, Z.:
    "Scandium-Catalyzed Silylation of Aromatic C-H Bonds"
    Angew. Chem. Int. Ed., 50, 10720-10723 (2011).
  5. Shima, T., Luo, Y. , Stewart, T. , Bau, R., Mclntyre, G. J., Mason, S. A., Hou, Z.:
    "Molecular heterometallic hydride clusters composed of rare-earth and d-trantion metals"
    Nature Chem., 3, 814-820 (2011).
  6. Guo, F., Nishiura, M., Koshino, H., Hou, Z.:
    "Scandium-Catalyzed Cyclocopolymerization of 1,5-Hexadiene with Styrene and Ethylene: Efficient Synthesis of Cyclopolyolefins Containing Syndiotactic Styrene-Styrene Sequences and Methylene-1,3-cyclopentane Units"
    Macromolecules, 44, 6335-6344 (2011).
  7. Chen, J., Shima, T., Hou,. Z.:
    "Rare-Earth Polyhydride Complexes Bearing Bis(phosphinophenyl)amido Pincer Ligands."
    Angew. Chem. Int. Ed. 50, 1857-1860 (2011).
  8. Zhang, L., Cheng, J., Ohishi , T., Hou, Z.:
    "Copper-Catalyzed Direct Carboxylation of C-H Bonds with Carbon Dioxide"
    Angew.Chem.Int.Ed., 49, 8670-8673 (2010).
  9. Hamashima, Y., Nagi, T., Shimizu, R., Tsuchimoto, T., Sodeoka, M.:
    "Catalytic Asymmetric α-Chlorination of 3-Acyloxazolin-2-one with a Trinary Catalytic System."
    Eur. J. Org. Chem., 3675-3678 (2011).
  10. Umebayashi, N., Hamashima, Y., Hashizume, D., Sodeoka, M.:
    "Catalytic Enantioselective Aldol-type Reaction of β-Ketoesters with Acetals."
    Angew. Chem. Int. Ed. 47, 4196-4199 (2008).

Members

Principal Investigator

Zhaomin HOU
Team Leader

Staff Scientist

Mikiko SODEOKA
Masayoshi NISHIURA
Senior Research Scientist
Takanori SHIMA
Senior Research Scientist
Masanori TAKIMOTO
Senior Research Scientist
Yoshihiro SOHTOME
Research Scientist

Postdoctoral Fellow

Jianhua CHENG
Contract Researcher
Juzo OYAMADA
Postdoctoral Researcher
Bingtao GUAN
Postdoctoral Researcher
Hongxia ZHANG
Postdoctoral Researcher
Koji NEMOTO
Postdoctoral Researcher

Administrative Assistant

Hiromi SUGIYAMA
Assistant